Surface and Nano Engineering Laboratory, SaNEL


-"Bottom-up" Nanofabrication by Self-assembly
-Multifunctional Nanocomposite Films
-Epitaxial Oxide and Composition Gradient Nanostructures
-Nanotribology, Ultra Low Friction Solid Films
-Surface Science and Engineering

   

Personnel

Laboratory Director: Efstathios (Stathis) I. Meletis, Professor

Graduate students:                                                   
Cristian Cionea (Ph.D.)   Desai Pruthul (MS)                       Michael Frink (MS)
Jie He (Ph.D.)                  Giancarlo Rios (MS)                     Yinsheng Fang (MS)
Hamed Arami Ph.D.)        Varad Sakhalkar (MS)      Anjana Shyamsundar (MS)
Razieh Khalifehzadeh (Ph.D.)

Recent Graduates: Pankaj Hazarika (MS), Gunjan Shebe (MS), Lee-Chun (Mandy) Su (MS), Hsu Chun Chen (MS).

Funding
NSF, DARPA, NIH, NASA, SERDP, DOE, DOT, NAVAIR, ARO, state and industrial sources.

Research Activities  
Research activities at SaNEL are concerned with basic and applied processing-structure-property relationship with emphasis on nanotechnology and small-scale materials (nano materials, surface treatments and layers, thin films, coatings, materials for MEMS and NEMS and nano devices). 

·    Vacuum and Electrolytic Plasma-assisted Processing
We have developed and work on surface engineering by novel (patented) vacuum and electrolytic plasma-assisted processes that can produce functionally gradient layers and surface films/coatings for a wide range of applications from aerospace to biomaterials. Vacuum processes are centered on intensified plasma-assisted nitriding for surface hardening, coating and surface modification treatments addressing surface-sensitive properties such as tribological, corrosion, biocompatibility and etc. Electrolytic plasma processing is a relatively new process that can combine effective cleaning and coating in a wet environment. Present activities are concerned with replacement of toxic electroplated Cd, Cr and Ni with environmentally friendly coatings.
·    Multifunctional, Nanoparticle and Multilayered Nanocomposites
In the nano-composite thin films area, we are focusing on nano-particle and nano-layered multifunctional films where the components act synergistically and can offer a combination of desirable properties (mechanical, tribological, magnetic, electronic, electrochemical, biological, biocompatibility, etc.). For example, one of the nano-composites we are currently pursuing is multifunctional Co-DLC (diamondlike carbon) films where self-assembling of 5 nm diameter Co nanorods can take place providing an excellent potential to use these films in high density storage, biosensors, MEMS, microdevices, etc. We also pursuing the possibility to use the self-organized Co structures as a nanocatalyst to grow guided arrays of single-wall CNTs that can lead to really exciting electronic applications.
·   Self-organized, Epitaxial Oxide Nanostructured Films

The last few years, we were the first to observe and report self-assembling in epitaxial perovskite -type oxide films. We currently exlpore ways to manipulate this process and to develop a novel “bottom-up” nanofabrication technique for sensors, optical, electronic and magnetic nanodevices.These research activities are supported by a NIRT/NSF grant.
·  Nanotribology
Research Activities Concentrate on (i) Ultra low friction nanocomposite DLC films and understanding nano particle effects on thin film wear behavior and (ii) understand scale effects on tribological behavior of nanostructured metals and ceramics.

Facilities
·  Plasma-assisted Material Processing
Intensified plasma-assisted nitriding system
* PVD/CVD vacuum system (DC, pulse and RF magnetron sputtering guns)
*Electrolytic plasma processing set-up (DC and pulse)

·  Mechanical Surface Testing/Tribology
*Pin-on-disc tribometer with lubrication/environmental cells (CSM    Instruments, TRB)

·  Electrochemical Testing/Corrosion
*Potentiostat/Galvanostat (EG&G 273), computer controlled and appropriate    software
*Stress corrosion cracking/Hydrogen embrittlement, alternate immersion     testing


Selected Publications
Wear Mechanism of Nanocrystalline Metals, Z.Q. Qi, J.C. Jiang and E.I. Meletis, Journal of Nanoscience and Nanotechnology (2008). [invited]

A Non-probe/lithography Approach to Nanotrench/Nanochannel Fabrication, X. Nie and E.I. Meletis, Int. J. Nanomanufacturing 2(1/2), 127-134 (2008).
Orientation Preferred Structures in BaTiO3 Thin Films on Ni Substrates, J.C. Jiang, E.I. Meletis, Z. Yuan, J. Liu, J. Weaver, C.L. Chen, B. Lin, V. Giurgiutiu, R.Y.Guo, A.S. Bhalla, D. Liu and K. W. White, Journal of Nano Research 1, 59-63 (2008).

Interface Modulated Structure of Highly Epitaxial (Pb,Sr)TiO3 Thin Films on (001) MgO, J.C. Jiang, Z. Yuan, C.L. Chen and E.I. Meletis, Applied Physics Letters 90, 051904 (2007).

Effects of N-doping on the Microstructure, Mechanical and Tribological Behavior of Cr-DLC Thin Films, S.K. Pal, J.C. Jiang and E.I. Meletis, Surface and Coatings Technology 201, 7917-7923 (2007).

Synthesis, Characterization and Properties of Intensified Plasma-assisted Nitrided IN-718 Superalloy, V. Singh and E.I. Meletis, Surface and Coatings Technology 201, 1093-1101(2006).

Ordered, Self-organized Co Nanodots in Co-Diamond-like Carbon Thin Films, E.I. Meletis and J.C. Jiang, Journal of Nanoscience and Nanotechnology 6(6), 1807-1810 (2006). (invited)

Nanofabrication by Self-organization of Three-dimensional Epitaxial Oxide Nanorods, J.C. Jiang and E.I. Meletis, Thin Solid Films 515, 39-45 (2006).
Local structure of Composite Cr-containing Diamond-like Carbon Thin Films, V. Singh, V. Palshin, R.C. Tittsworth and E.I. Meletis, Carbon 44(7), 1280-1286(2006).