College of Science News
UTA researchers find cheaper, less energy-intensive way to purify ethylene, the raw material for widely used plastics, industrial compounds
Researchers at The University of Texas at Arlington have filed a provisional patent application on a new copper compound that can be used to purify ethylene for use as a raw material in the production of plastics such as polyethylene or PVC, as well as other industrial compounds.
Ethylene is produced from crude oil but is usually obtained as a mixture containing ethane. Manufacturing processes using ethylene usually require pure, or 99.9 percent, ethylene feed-stock.
“Existing technologies to separate ethylene and ethane use enormous amounts of energy and require high levels of capital investment,” said Rasika Dias, UTA distinguished university professor of chemistry and biochemistry. “Our new technology uses a copper compound that can selectively absorb ethylene in the solid state, leaving ethane out, with the minimum amount of energy release.”
Ethylene absorption by the newly discovered copper complex is easily reversible, so the absorbed ethylene can then be released and recovered using mild temperature or pressure changes, resulting in the regeneration of the starting copper complex, which can be reused multiple times.
“As a result, our new technology is both highly sustainable and very energy-efficient, and could represent a real breakthrough in the separation of olefins like ethylene and propylene from paraffins, which currently accounts for 0.3 percent of global energy use, roughly equivalent to Singapore’s annual energy consumption,” Dias said.
The researchers reported their new technology in the October 17 edition of the international journal Angewandte Chemie, in an article titled “Low net heat of adsorption of ethylene achieved by major solid‐state structural rearrangement of a discrete copper complex.” The paper describes how the release of a very low level of heat during the absorption process is the result of the accompanying structural rearrangement of the copper complex upon exposure to ethylene.
Co-authors include Naleen Jayaratna, a lecturer in chemistry at Rajarata University of Sri Lanka who earned his Ph.D. from UTA in 2016; Devaborniny Parasar, a fourth-year doctoral student in Dias’ lab; Matthew Cowan, Hans Funke, and Richard Noble of the Department of Chemical and Biological Engineering at the University of Colorado at Boulder; Joseph Reibenspies of the Department of Chemistry at Texas A&M University; Pavel Mykhailiuk of Enamine Ltd., in Kyiv, Ukraine; and Oleksii Artamonov of Selvita S.A., in Krakow, Poland.
Fred MacDonnell, professor and chair of the UTA Department of Chemistry and Biochemistry, congratulated Dias on the development of this new technology.
“Dr. Dias and his colleagues have taken on the challenge of improving one of the most relevant chemical separations, and one needed for multiple industrial processes and the production of products used throughout our daily lives,” MacDonnell said. “This could have very important implications for the costs associated with producing these goods, and also radically improve the environmental impact by reducing the heat emitted to the atmosphere.”