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Richard B. Timmons |
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Physical
Chemistry
Distinguished Professor B.S. St. Francis Xavier University (1958) Ph.D. The Catholic University of America (1962) Postdoctoral Fellow:
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Phone: 817-272-3801 FAX: 817-272-3808 E-mail: timmons@uta.edu Office: 234a SH Personal Page |
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Awards and Honors Appointed Distinguished University Professor and Member of the UTA Academy of scholars (2007) RESEARCH INTERESTS Surface Science The major focus of our laboratory, for the past 15 years, has been development and application of technology to provide molecular surface tailoring of materials. For this purpose, we employ plasma enhanced chemical vapor depositions to deposit conformal, thin film coatings on a wide variety of substrates. In particular, we have developed a variable duty cycle pulsed plasma technique which provides exceptional control of chemistry during plasma polymerization depositions of thin films. This film chemistry controllability permits variation and adjustment of the surface energies of virtually any solid substrate. Additionally, our technological provides an unusually simple and versatile approach to introduction of a wide range of surface chemical functionalities. These functional groups can subsequently be employed for attachment of target compounds, thus creating 3-dimensional molecularly designed surfaces. Recently, we have extended this gas phase surface modification technology to include precise surface tailoring of fine powders, including particles as small as 20 nanometers. We are currently involved in evaluation of our molecular tailoring capability, with a major emphasis on a variety of nanotechnology applications. Among these studies are synthesis of new materials which focus on achieving improved dispersion and bonding of inorganic nanoparticles in organic matrices, to provide improved electrical and thermal properties for these interesting new nanocomposites. We are also studying several new approaches involving molecularly tailored nanoparticles and other materials for use in drug delivery and antimicrobial coatings, as well as a variety of additional biomaterials and catalytic applications. Representative
Publications:
Ogawa, D., Saraf, I., Sra,A., Timmons, R., Goeckner, M., and Overzet, L.
“The direct injection of liquid droplets into low pressure plasmas”,
J. Vac. Sci. & Technology, A,
27: 342-351,
Bhattacharyya, D.,Yoon, W.-J., Berger, P.R., Timmons, R.B.
“Plasma-polymerized multistacked organic bipolar films: A new approach to flexible high-k dielectrics“,
Advanced Materials,
20: 2383-2388,
Thevenot , P., Cho, J., Wavhal, D., Timmons, R.B., Tang., L.
“Surface chemistry influences cancer killing effect of TiO2 nanoparticles“,
Nanomedicine : Nanotechnology, Biology, and Medicine,
4: 226-236,
Kamath, D., Bhattacharyya , D., Padukudru , C., Timmons, R.B., Tang, L.
“Surface chemistry influences implant-mediated host tissue responses“,
J.Biomed. Maters. Res. Part A,
86: 617-626,
Chapman, C.L., Bhattacharyya, D., Eberhart, R.C., Timmons, R.B., Chuong, C.
“Plasma polymer thin film depositions to regulate gas permeability through nanoporous track etched membranes“,
J. of Membrane Science,
318: 137-144,
Dennis, B.H., Jin, W., Cho,J., Timmons, R.B.
“Inverse determination of kinetic rate constants for transesterification of vegetable oils“,
Inverse Problems in Science and Engineering,
16: 693-704,
Nair, A., Zou, L., Bhattacharyya, D., Timmons, R. B., Tang, Liping.
“Species and density of implant surface chemistry affect the extent of foreign body reactions“,
Langmuir,
24: 2015-2024,
Bhattacharyya, D., Pillai, K., Chyan O., Tang L., Timmons R.B.
“A new class of thin film hydrogels produced by plasma polymerization“,
Chemistry of Materials,
19: 2222-2228,
Xu, Y.; Berger, P.R.; Cho, J.; Timmons, R.B.
“Pulsed plasma polymerized dichlorotetramethyl-disiloxane high-k gate dielectrics for polymer field-effect transistors“,
Journal of Applied Physics,
99: 1-4,
Cho, J.; Denes, F.S.; Timmons, R.B.
“Plasma processing approach to molecular surface tailoring of nanoparticles: Improved photocatalytic activity of TiO2“,
Chemistry of Materials,
18: 2989-2996,
Ma Y.; Manolache, S.; Denes, F.S.; Cho, J.; Timmons, R.B.
“Surface modification of rutile TiO2 by submerged arc discharge for improved photoreactivity“,
Journal of Materials Engineering and Performance,
15: 370-375,
Susut C.; Timmons, R.B.
“Plasma enhanced chemical vapor depositions to encapsulate crystals in thin polymeric films: A new approach to controlling drug release rates“,
International Journal of Pharmaceutics,
288:253-261,
Li, M.L.; Timmons, R.B.; Kinsel, G.R.
“Radio frequency plasma polymer coatings for affinity capture MALDI mass spectrometry“,
Analytical Chemistry,
77: 350-353,
Xu Y.F., Berger, P.R., Cho, J., Timmons, R.B.
“Capacitance-voltage characterization of pulsed plasma polymerized allylamine dielectrics for flexible polymeric field effect transistors“,
Journal of Electronic Materials,
33: 1240-1247,
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Department of Chemistry and Biochemistry |
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